Synthesis of a Coal Fly Ash‐Based NaP Zeolite Using the Microwave‐Ultrasonic Assisted Method: Preparation, Growth Mechanism, and Kinetics

Author:

Liu Yixuan1,Zhou Tengteng1,Chen Xingxing1,Li Hua2,Xu Xiuli13,Dou Jinxiao1ORCID,Yu Jianglong14

Affiliation:

1. Key Laboratory for Advanced Coal and Coking Technology of Liaoning Province School of Chemical Engineering University of Science and Technology Liaoning Anshan China

2. School of Molecular Sciences University of Western Australia Crawley WA Australia

3. Sinosteel Anshan Research Institute of Thermo-Energy Co. Ltd Liaoning 114044 China

4. Suzhou Industrial Park Monash Research Institute of Science and Technology and Southeast University-Monash University Joint Graduate School Suzhou 215123 China

Abstract

AbstractFly ash was used as the raw material to prepare coal fly ash‐based NaP zeolite using the microwave‐ultrasonic‐hydrothermal method. The obtained NaP zeolite has a completed crystal structure, regular surface morphology, uniform particle size (about 1.6 um), large specific surface area (48.85 m2/g) and good thermal stability. Under microwave and ultrasonic external fields, the coal fly ash‐based NaP zeolite crystals grow in an S‐shape, achieving single crystal growth and uniform crystal growth size. The activation energy of NaP zeolite crystal growth Ea is 2.08 kJ/mol, the pre‐exponential factor A is 85.63.

Funder

Natural Science Foundation of Liaoning Province

Publisher

Wiley

Subject

General Chemistry

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