Affiliation:
1. Applied Organic Chemistry Chemical Sciences & Technology Division CSIR-North East Institute of Science and Technology 785006 Jorhat India
2. Academy of Scientific and Innovative Research (AcSIR) 201002 Ghaziabad India
3. Jubilant Biosys Ltd. 201306 Greater Noida India
4. Indian Institute of Technology-Guwahati Department of Chemistry Guwahati 781039 Assam India
Abstract
AbstractThe combination of organometallic C−H activation and electro‐catalysis has emerged as a potent synthetic technique for various molecular scaffolds since it avoids the use of harmful and expensive chemical oxidants in stoichiometric amounts. Moreover, the pre‐functionalization of substrates is not required and newer ways to perform metal‐catalyzed C−H activation reactions are possible. Here, we have discussed eletrochemically driven C−H acyloxylation, acetoxylation, oxygenation, acylation, amination, alkylation, halogenation, olefinations and C−H/N−H annulation reactions using various transition‐metal‐catalyst such as Ru, Rh, Pd, Co, Ni, Ir, Cu, Mn and Au by anodic oxidation, followed by reductive elimination to form the corresponding C−O, C−C, C−N and C−X (X=Cl, Br, S etc.) bonds. This review covers recent developments in transition‐metal‐catalyzed electrochemical C−H activation from 2007 until 2022.
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3 articles.
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