Tropylium‐BF<sub>4</sub>as Organocatalyst for Microwave‐assisted Beckmann rearrangement in [TMG][BF<sub>4</sub>]: One‐pot conversion of Ketones to Amides-Reference-Cited by-同舟云学术

Tropylium‐BF₄as Organocatalyst for Microwave‐assisted Beckmann rearrangement in [TMG][BF₄]: One‐pot conversion of Ketones to Amides

Published:2023-06-13 Issue:23 Volume:8 Page:
ISSN:2365-6549
Container-title:ChemistrySelect
language:en
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Author:

Anchi Athmanand¹,Kalkhambkar Rajesh G.¹^ORCID,Sutar Suraj M.²,Naik Ravi S.³,Refat Moamen S.⁴,Adam Abdel Majid A.⁴,Mohammed Alsuhaibani Amnah⁵

Affiliation:

1. Department of Chemistry Karnatak University's Karnatak Science College, Dharwad Karnataka 580001 India

2. Department of Chemistry Yashwantrao Chavan Mahavidyalaya, Halkarni Maharashtra 416552 India

3. Department of Chemistry Mahantswami Arts, Science and Commerce College College, Haunsbhavi Karnataka 581109 India

4. Department of Chemistry, College of Science Taif University Taif 21944 Saudi Arabia

5. Department of Physical Sport Science, College of Education Princess Nourah bint Abdulrahman University Riyadh 11671 Saudi Arabia

Abstract

AbstractThe microwave assisted one pot efficient conversion of ketones into respective amides has been achieved by utilization of environmentally benign catalytic system tailored by tropylium tetrafluoroborate (Tp+BF−4) and 1,1,3,3‐tetramethylguanidinium tetrafluoroborate [TMG][BF4]. The mild reaction conditions, shorter reaction time, and affordable catalytic system are the key points that highlight the importance. The high product yield and ease of recycling impacts the successful product conversion.

Publisher

Wiley

Subject

General Chemistry

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