Metal‐Free Visible‐Light‐Promoted Haloazidation/Cyclization of Phenyl‐Linked 1,6‐Enynes with TMSN<sub>3</sub> and NIS/NBS**-Reference-Cited by-同舟云学术

Metal‐Free Visible‐Light‐Promoted Haloazidation/Cyclization of Phenyl‐Linked 1,6‐Enynes with TMSN₃ and NIS/NBS**

Published:2023-08-02 Issue:29 Volume:8 Page:
ISSN:2365-6549
Container-title:ChemistrySelect
language:en
Short-container-title:ChemistrySelect

Author:

Hu Lin‐Ping¹,Zhang De‐Run¹,Liu Feng‐Lin¹,Huang Xiao‐Hong¹,Li Xia²,Teng Ming‐Yu¹^ORCID,Liu Bo¹,Huang Guo‐Li¹^ORCID

Affiliation:

1. School of Chemistry and Chemical Engineering Yunnan Normal University 650500 Kunming China

2. Department of Library Yunnan Normal University 650500 Kunming China

Abstract

AbstractA metal‐ and oxidant‐free procedure for the three‐component haloazidation/cyclization of phenyl‐linked 1,6‐enynes with TMSN3 and N‐iodo(bromo)succinimide under the irradiation of visible light was described. Moreover, this reaction involved a radical addition/5‐exo‐dig cyclization/radical coupling process, and realized simultaneous construction of C−N, C−C, and C−X (I, Br) bonds in one step.

Funder

National Natural Science Foundation of China

Publisher

Wiley

Subject

General Chemistry

Reference60 articles.

2. Cyclization Cascades via N-Amidyl Radicals toward Highly Functionalized Heterocyclic Scaffolds

3. Metal-Free Radical5-exo-dig Cyclizations of Phenol-Linked 1,6-Enynes for the Synthesis of Carbonylated Benzofurans

4. Development of Cascade Reactions for the Concise Construction of Diverse Heterocyclic Architectures

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