The Role of V‐Species and O‐Species on Controlled‐Hydrogen‐Reduction VOx Surfaces in Cyclohexane Oxidation

Author:

Li Yingwei12,Chen Shengxin1,Jin Ying3,Li Xinxin3,Zhang Ruirui12,Liu Ruixia123ORCID

Affiliation:

1. Beijing Key Laboratory of Ionic Liquids Clean Process CAS Key Laboratory of Green Process and Engineering State Key Laboratory of Multiphase Complex Systems Institute of Process Engineering Innovation Academy for Green Manufacture Chinese Academy of Sciences 1 North 2nd Street, Zhongguancun, Haidian District Beijing 100190 China

2. School of Chemical Engineering University of Chinese Academy of Sciences Yuquan Road, Shijingshan District Beijing 100049 China

3. Zhengzhou Institute of Emerging Industrial Technology Jinke zhihui Valley Hongyuan Road, Jinshui District Zhengzhou 450000 China

Abstract

AbstractA series of controlled‐hydrogen‐reduction VOx (CHR‐VOx) were prepared after our controllable hydrogen treatment, and CHR‐VOx were controlled to be reduced to the states dominated by V5+ and V4+ species, subsequently the catalytic roles of V‐species and O‐species for cyclohexane (CHA) oxidation were explored. As expected, the surface properties of CHR‐VOx have occurred remarkable change resulting in a significantly improvement on catalytic performance determined by V‐species and O‐species. The reduction behavior of the properties was recognized by XPS and Raman. Generally, the moderate‐reduced CHR‐VOx which possessed most 78.7 % multi‐liganded‐oxygen (LO) performed the best conversion for CHA (11.8 %), and the over‐reduced CHR‐VOx with a large content of V4+ species (33 %) performed a best selectivity for adipic acid (44.3 %). In this case, LO sites were regarded as the active site to accelerate the activation of CHA, while V4+ species were regarded as the oxygen vacancies (OVs) through V4+−OV to contribute to the further oxidation to adipic acid.

Funder

National Outstanding Youth Science Fund Project of National Natural Science Foundation of China

National Natural Science Foundation of China

Dalian National Laboratory for Clean Energy

Publisher

Wiley

Subject

General Chemistry

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