A Facile Zinc(II) Chloride Assisted Desulfurization of High‐Nitrogen Heterocycles

Author:

Zuckerman Jake E.12ORCID,Zeller Matthias3,Piercey Davin G.124ORCID

Affiliation:

1. School of Materials Engineering Purdue University 701 W. Stadium Avenue West Lafayette IN 47906

2. Purdue Energetics Research Center Purdue University 205 Gates Road West Lafayette IN 47906

3. Department of Chemistry Purdue University 560 Oval Drive West Lafayette IN 47907

4. Department of Mechanical Engineering Purdue University 585 Purdue Mall West Lafayette IN 37906

Abstract

AbstractHigh‐nitrogen heterocycles are important to fields as diverse as pharmaceuticals and energetic materials. However, their synthesis can often be inconvenient or involve toxic precursors. In this work, we synthesize 1‐substituted‐5H‐tetrazoles via the desulfurization of readily available 1‐substituted‐1H‐tetrazole‐5‐thiones via a zinc chloride assisted desulfurization providing a new, safe, and efficient process with higher yields than the traditional desulfurization methods.

Funder

Purdue University

Publisher

Wiley

同舟云学术

1.学者识别学者识别

2.学术分析学术分析

3.人才评估人才评估

"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370

www.globalauthorid.com

TOP

Copyright © 2019-2024 北京同舟云网络信息技术有限公司
京公网安备11010802033243号  京ICP备18003416号-3