From Alkenes to Cyclic Carbonates with a Stable Iron‐Cross‐Bridged Cyclam Catalyst

Author:

Yeamin Md Bin1,Annunziata Alfonso2,Ruffo Francesco3,Masdeu‐Bultó Anna M.1ORCID

Affiliation:

1. Department of Physical and Inorganic Chemistry Universitat Rovira i Virgili Carrer Marcel⋅lí Domingo, 1. Campus Sescelades 43007 Tarragona Spain

2. Institut Català d'Investigacions Químiques (ICIQ) Avda. Països Catalans, 16 43007 Tarragona Spain

3. Dipartimento di Scienze Chimiche Università di Napoli Federico II and CIRCC Complesso Universitario di Monte S. Angelo Via Cintia 21 80126 Napoli Italy

Abstract

AbstractA stable iron(III) complex with the cross‐bridged cyclam 4,11‐dimethyl‐1,4,8,11‐tetraazabicyclo[6.6.2]hexadecane catalyzes the epoxidation of aromatic alkenes and the fixation of CO2 into cyclic carbonates. Best results were obtained for styrene conversion to styrene carbonate.

Publisher

Wiley

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