In Situ Growth of CdS Nanoparticles Between g‐C3N4 Layers for Photocatalytic Reduction of Nitrobenzene

Author:

Tian Zongju1,Han Jun1,Wu Fangzhou1,Chen Xiyu1,Hu De1,Yu Feng1,Qi Kezhen2,Wang Wei13ORCID

Affiliation:

1. School of Chemistry and Chemical Engineering/State Key Laboratory Incubation Base for Green Processing of Chemical Engineering Shihezi University Shihezi 832003 China

2. Institute of Catalysis for Energy and Environment College of Chemistry and Chemical Engineering Shenyang Normal University Shenyang 110034 China

3. School of Chemical Engineering Shandong Institute of Petroleum and Chemical Technology Shandong 257061 China

Abstract

AbstractPhotocatalysis technology is green and sustainable for reduction of nitrobenzene to aniline. However, the photocatalytic activity of pure carbon nitride is limited by the high photogenerated carrier recombination rates. Carbon nitride nanosheets (CNN) were prepared by prepolymerization and high temperature calcination and cadmium sulfide (CdS) nanoparticles were in situ grown between the layers of carbon nitride for facilitating the separation and transfer of charges. As a result, the optimal composite catalyst (CdS/CNN‐2) exhibited superior photocatalytic activity with nitrobenzene reduction rate of 83 % within 60 min. This work presents an effective strategy for designing catalysts for the photocatalytic reduction of nitrobenzene.

Funder

National Natural Science Foundation of China

Publisher

Wiley

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