An Ammonia Gas Sensor Based on Reduced Graphene Oxide Nanocomposite Hydrogels

Author:

Saleh Asala M.1,Albiss Borhan A.1,Al‐Rawashdeh Nathir A. F.2ORCID,Alsharaeh Edreese H.3

Affiliation:

1. Jordan University of Science and Technology Nanotechnology Institute P.O.Box 3030 Irbid 22110 Jordan

2. Jordan University of Science and Technology Chemistry Department P.O. Box 3030 Irbid 22110 Jordan

3. Alfaisal University, College of Science and General Studies P.O. Box 50927 Riyadh 11533 Saudi Arabia

Abstract

AbstractA flexible gas sensor based on nanocomposite has been developed and characterized for detecting ammonia gas (NH3) in the atmosphere. This sensor utilizes nanocomposite hydrogels composed of Arabic gum (AG), acrylic acid (AAc), reduced graphene oxide (RGO), and silver nanoparticles (AgNPs). Various techniques, including FTIR (Fourier Transform Infrared Spectroscopy), AFM (Atomic Force Microscopy), XRD (X‐ray Diffraction), SEM (Scanning Electron Microscopy), XRF (X‐ray Fluorescence), TGA (Thermo‐gravimetric Analysis), DSC (Differential Scanning Calorimetry), were used to evaluate the sensor‘s properties. The nanocomposite hydrogels showed exceptional swelling ability (597 %), advantageous for accommodating gas molecules like NH3. The Polymerization and network formation percentages of 31 % and 56 %, respectively, suggest a robust hydrogel matrix structure. When tested for NH3 gas sensing at room temperature, the RGO/AgNPs/AGPAAc‐hydrogel exhibited high sensitivity and stability compared to other variants across gas concentrations ranging from 0 to 100 ppm. The improved performance of the physiochemical properties of the nanocomposite hydrogels might be attributed to the combined effect of AgNPs and RGO, which likely enhance sensitivity and stability. Selectivity tests conducted for three gases at room temperature revealed that the sensor response was highly selective to NH3 at a concentration of 50 ppm. Furthermore, the sensor demonstrated consistent performance over time. These findings suggest potential applications in environmental monitoring and industrial safety, with the possibility of contributing to advancements in gas sensing technology and addressing environmental and safety concerns.

Funder

Deanship of Research, Jordan University of Science and Technology

Publisher

Wiley

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