Affiliation:
1. Department of Chemistry Materials and Chemical Engineering “Giulio Natta” Politecnico di Milano Via Luigi Mancinelli 7 20131 Milano Italy
Abstract
AbstractBy combining isoquinoline‐5‐carboxilic acid with Cu(II) ions under several different conditions, we were able to obtain novel metallorganic materials, among which two 2D coordination polymers, CP 1 and CP 2 which were also characterized by SC‐XRD. Ratio of solvents (EtOH : DMF) in the mixture employed during their synthesis has a marked effect in selecting the formation of one species or the other, which basically differ in the coordination at the Cu(II) center due to k1/k2 denticity of the carboxylate ligands.
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