AgO@InGaZnO4 composites for environmental photocatalysis

Author:

Yang Jia12ORCID,Liu Miaomiao1,Liao Lingshan1,Li Yan3,Wang Huijun1,Huang Huisheng1,Jiang Pengfei4,Sun Xiaorui1ORCID

Affiliation:

1. Chongqing Key Laboratory of Inorganic Special Functional Materials College of Chemistry and Chemical Engineering Yangtze Normal University, Fuling Chongqing 408100 P. R. China

2. Guangxi Ministry-Province Jointly-Constructed Cultivation Base for State Key Laboratory of Processing for Nonferrous Metal and Featured Materials College of Materials Science and Engineering Guilin University of Technology Guilin 541004 P. R. China

3. Guangxi Key Laboratory of Electrochemical and Magnetochemical Functional Materials College of Chemistry and Bioengineering Guilin University of Technology Guilin 541004 P. R. China

4. College of Chemistry and Chemical Engineering Chongqing University Chongqing 401331 P. R. China

Abstract

AbstractWe reported AgO@InGaZnO4 as a novel photocatalyst for environmental photocatalysis. X‐ray diffraction, Raman spectrum, fluorescence spectroscopy, fourier infrared spectroscopy, scanning electron microscope, X‐ray photoelectrons spectroscopy, and electrochemical tests were utilized to identify the composition, chemical valence states, morphology, and photocatalytic potential of AgO@InGaZnO4. In the experiments of photo‐reduction Cr(VI) ion and photodegradation Rhodamine B (RhB) reactions, the kinetic constants of AgO@InGaZnO4 samples are 1.7 and 7.1 times of the parent, respectively. The analysis of photocatalytic mechanism indicates that AgO acts as an electron trap to promote photogenerated charge separation and enhance photocatalytic performance. Moreover, AgO also plays an important role in the adsorption of the catalyzed substrate in the composite.

Funder

Chongqing Municipal Education Commission

Publisher

Wiley

Subject

General Chemistry

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