Porosint‐Supported PVDF Derivatives with Good Adsorption Performance and Recyclability for the Removal of Aqueous Heavy Metal Ions

Abstract

AbstractHeavy metal ions in water can affect human health. Taking Pb2+ for an example, it can lead to kidney failure and tumor infection. Polyvinylidene fluoride (PVDF) has been widely used as filter membranes in wastewater treatment. This paper uses citric acid (CA) as the connecting arm to graft carboxymethyl chitosan (CMCS) onto PVDF and prepare a novel granular molecular sieve‐supported PVDF derivative (s‐PVDF‐CA‐CMCS). The structure was characterized and the adsorption capacity for heavy metal ions was investigated. The results indicate that s‐PVDF‐CA‐CMCS has good adsorption performance for aqueous heavy metal ions, especially for Pb2+, with a removal rate of 99.39 % and an adsorption capacity of 198.41 μg/g. The adsorption data fits the pseudo‐second‐order kinetic model (R2=0.9992), and the removal rate of Pb2+ was 78.48 % after 5 cycles of adsorptions, indicating that s‐PVDF‐CA‐CMCS may be potential applications for removing heavy metal ions in water treatment.