Sustainable Synthesis and Characterizationof Corncob‐Derived Graphene Oxide

Author:

Tinh Ninh Thi123,Dat Nguyen Minh123,Hieu Le Minh123,Bao Le Minh123,Khoa Nguyen Nhat123,Nhan Dang Duc123,Hoang Tat Minh123,Bao Pham Phi123,Huong Quach Thi Thanh123,Hanh Nguyen Thi123,Huong Le Minh123,Khang Pham Tan123,Danh Tong Thanh123,Hieu Nguyen Huu123ORCID

Affiliation:

1. VNU-HCM Key Laboratory of Chemical Engineering and Petroleum Processing (Key CEPP Lab) Ho Chi Minh City University of Technology (HCMUT) 268 Ly Thuong Kiet Street Ho Chi Minh City Vietnam

2. Faculty of Chemical Engineering Ho Chi Minh City University of Technology (HCMUT) 268 Ly Thuong Kiet Street Ho Chi Minh City Vietnam

3. Vietnam National University Ho Chi Minh City (VNU-HCM) Linh Trung Ward, Thu Duc City, Ho Chi Minh City Vietnam

Abstract

AbstractRecently, though graphene oxide (GO) has shown promising applications in many fields, there have not been many studies focusing on exploiting the source of synthetic precursors of GO. Herein, GO was synthesized from the cellulose of corncob by corncob alkalization, bleaching cellulose, pyrolysis, and improved Hummer's method. It was found that pyrolysis plays an important role in the graphitization of cellulose precursors with the catalyst Fe(NO3)3 to form Gi‐Fe(NO3)3. The GO material synthesized from Gi‐Fe(NO3)3 was characterized by advanced analytical methods. The X‐ray diffraction pattern of Gi‐Fe(NO3)3 shows the formation of a diffraction peak at the crystal plane (002), which is characteristic of the graphite material. The synthesized GO underwent a series of changes in material structure and morphology, which are confirmed via transmission electron microscopy images showing a plate‐like structure with folds represented by the dark line. This study demonstrates a sustainable approach that directly utilizes abundant biomass resources for the synthesis of GO material.

Publisher

Wiley

Subject

General Chemistry

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