II2. Anwendungsmöglichkeiten und Begrenzungen der polarographischen Methode zur Verfolgung schneller chemischer Reaktionen in Lösungen

Abstract

AbstractThe conditions of the reaction layer near the electrode surface caused by a rapid chemical reaction controlling the electrode process is discussed. The limits of the rate constants which can be obtained by polarographic kinetic currents are determined. The case is considered where the reaction layer is partially or completely in the diffusion part of the electrode double layer. Chemical reactions which control the electrode process without complicating influences are cited.