Recent Applications of Paired Electrolysis in Organic Synthesis

Author:

Jiao Ke‐Jin1,Gao Xiao‐Tong2,Ma Cong3,Fang Ping3,Mei Tian‐Sheng3ORCID

Affiliation:

1. College Chemistry Chongqing Normal University Chongqing 401331 China

2. School of Chemistry and Chemical Engineering Chongqing University of Science & Technology Chongqing 401331 China

3. State Key Laboratory of Organometallic Chemistry Center for Excellence in Molecular Synthesis Shanghai Institute of Organic Chemistry University of the Chinese Academy of Sciences Chinese Academy of Sciences 345 Lingling Road Shanghai 200032 China

Abstract

AbstractRecent years have witnessed a renaissance of organic electrochemistry since the cheap, safe, sustainable electron could be employed as a traceless redox agent to facilitate redox conversions. Additionally, divergent selectivity could be achieved by tuning the potential or current of the electrochemical reaction. Compared to electrooxidation or electroreduction reactions, paired electrolysis represents a more practical and energy‐efficient strategy that delivers the products by making use of both anodic and cathodic reactions simultaneously. This mini‐review summarized the breakthroughs and recent advances in this fascinating field and mainly is divided into three parts: parallel, sequential, and convergent paired electrolysis.

Funder

Chongqing Municipal Education Commission

National Natural Science Foundation of China

Publisher

Wiley

Subject

General Chemistry

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