Affiliation:
1. Key Laboratory for Advanced Materials and Feringa Nobel Prize Scientist Joint Research Center Department of Fine Chemistry and Institute of Fine Chemicals School of Chemistry and Molecular Engineering East China University of Science and Technology 130 Meilong Road Shanghai 200237 P. R. China
Abstract
AbstractOur research interest focusing on synthetic methodology with diaryliodonium salts, is summarized in this account. Besides employing a dual activation strategy of C−I and ortho C−H bonds, we have introduced vicinal functional groups at ortho‐positions of diaryliodonium salts, in which their unique reactivities have been explored in various processes, including arylation, diarylation, cascade annulation, benzocyclization, arylocyclization, and intramolecular aryl migration. The variety of mechanisms of these reactions that involves either transition metals, especially palladium in organometallic catalysis, or transition‐metal free conditions, were discussed in the context.
Subject
Materials Chemistry,General Chemical Engineering,Biochemistry,General Chemistry
Cited by
10 articles.
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