Affiliation:
1. Key Laboratory of Catalysis and Energy Materials Chemistry of Ministry of Education & Hubei Key Laboratory of Catalysis and Materials Science & Key Laboratory of Analytical Chemistry of the State Ethnic Affairs Commission School of Chemistry and Materials Science South-Central Minzu University Wuhan 430074 China
2. Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education Hangzhou Normal University Hangzhou 311121 China
Abstract
AbstractAromatic organoboron compounds are highly valuable building blocks in organic chemistry. They were mainly synthesized through aromatic C−H and C−Het borylation, in which transition metal‐catalysis dominate. In the past decade, with increasing attention to sustainable chemistry, numerous transition metal‐free C−H and C−Het borylation transformations have been developed and emerged as efficient methods towards the synthesis of aromatic organoboron compounds. This account mainly focuses on recent advances in transition metal‐free aromatic C−H, C−N, C−S, and C−O borylation transformations and provides insights to where further developments are required.
Funder
National Natural Science Foundation of China
Subject
Materials Chemistry,General Chemical Engineering,Biochemistry,General Chemistry
Cited by
4 articles.
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