Affiliation:
1. School of Mechanics and Safety Engineering Zhengzhou University Zhengzhou China
Abstract
AbstractA combination of experimental and simulation methods is adopted to study the relationship between micro‐stress and micro‐strain of a single spherulite upon uniaxial tensile deformation. To verify the simulation results and establish a suitable spherulite model, large‐sized isotactic polypropylene spherulite is first cultured with isothermal crystallization, whose structural deformation upon application of uniaxial tension is recorded using a polarizing optical microscope. A nanoindenter is used to measure the elastic modulus of the spherulite and amorphous region, preparing the property parameters for numerical simulation. Modeling and meshing of the single spherulite are conducted with the finite element software ABAQUS. The entire deformation of the spherulite is analyzed with fixed strain as the boundary condition, and the microscopic stress and strain distribution inside and outside of the spherulite is obtained. The higher micro‐stress region mainly locates at two poles in the equatorial direction, where might be the origin of craze. Generally, the simulation result is basically consistent with the experimental deformation process, which provides a new idea for the study of microscale structure and performance. © 2024 Society of Chemical Industry.