Affiliation:
1. Department of Chemical and Materials Engineering University of Alberta Edmonton Alberta Canada
Abstract
AbstractOf the processes that are approved to produce synthetic kerosene for use in jet fuel, about half produce olefinic kerosene that is hydrotreated. The alkene concentration in synthetic kerosene is indirectly regulated through the thermal oxidative stability specification. Perceptions about the deleterious influence of alkenes on thermal oxidative stability suggest that olefinic kerosene must be deeply hydrogenated. The extent of olefin saturation required has economic implications. To evaluate what an acceptable alkene concentration in synthetic kerosene is, the impact of alkene concentration on the outcome of the jet fuel thermal oxidative stability test (JFTOT) performed at 325°C in accordance with the ASTM D3241 standard test method was experimentally evaluated. Model synthetic kerosene mixtures to which different concentrations of alkenes (1‐decene, α‐methylstyrene, indene) were added, as well as control samples were studied. In the concentration range investigated, up to 10 wt% 1‐decene, 5 wt% α‐methylstyrene, and 2 wt% indene did not lead to increased fouling in the JFTOT. Fouling passed through a minimum value with increasing alkene concentration and alkene concentration on its own was a poor predictor of thermal oxidative stability. Analysis of the kerosene collected after passing through the JFTOT found measurable changes in density and refractive index. Dissolved oxygen reacting during thermal oxidative stability testing was accounted for mostly in oxygen‐containing products in the kerosene boiling range, which indicated that the heavier products were mainly hydrocarbon in nature. In addition to initiation by autoxidation, the investigation also pointed to the existence of a second thermally initiated fouling pathway that does not require the presence of oxygen.