Pushing the Limits of Capillary Assembly for the Arbitrary Positioning of Sub‐50nm Nanocubes in Printable Plasmonic Surfaces

Author:

Capitaine Anna1,Fajri Muhammad L.1,Sciacca Beniamino1

Affiliation:

1. Aix‐Marseille Univ, CNRS, CINaM Campus de Luminy Marseille 13009 France

Abstract

AbstractThe fabrication of high quality nanophotonic surfaces for integration in optoelectronic devices remains a challenge because of the complexity and cost of top–down nanofabrication strategies. Combining colloidal synthesis with templated self‐assembly emerged as an appealing low‐cost solution. However, it still faces several obstacles before integration in devices can become a reality. This is mostly due to the difficulty in assembling small nanoparticles (<50 nm) in complex nanopatterns with a high yield. In this study, a reliable methodology is proposed to fabricate printable nanopatterns with an aspect ratio varying from 1 to 10 and a lateral resolution of 30 nm via nanocube assembly and epitaxy. Investigating templated assembly via capillary forces, a new regime was identified that was used to assemble 30–40 nm nanocubes in a patterned polydimethylsiloxane template with a high yield for both Au and Ag with multiple particles per trap. This new method relies on the generation and control of an accumulation zone at the contact line that is thin as opposed to dense, displaying higher versatility. This is in contrast with conventional wisdom, identifying a dense accumulation zone as a requirement for high‐yield assembly. In addition, different formulations are proposed that can be used for the colloidal dispersion, showing that the standard water‐surfactant solutions can be replaced by surfactant‐free ethanol solutions, with good assembly yield. This allows to minimize the presence of surfactants that can affect electronic properties. Finally, it is shown that the obtained nanocube arrays can be transformed into continuous monocrystalline nanopatterns via nanocube epitaxy at near ambient temperature, and transferred to different substrates via contact printing. This approach opens new doors to the templated assembly of small colloids and could find potential applications in various optoelectronic devices ranging from solar cells to light‐emitting diodes and displays.

Funder

Agence Nationale de la Recherche

Publisher

Wiley

Subject

General Materials Science,General Chemistry

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