Affiliation:
1. Institute of Industrial Catalysis, School of Chemical Engineering and Technology Xi'an Jiaotong University Xi'an 710049 P. R. China
2. Novel Energy Materials & Catalysis Research Center Shanwei Innovation Industrial Design & Research Institute Shanwei 516600 P. R. China
3. Division of Energy Storage, Dalian Institute of Chemical Physics Chinese Academy of Sciences Dalian 116023 P. R. China
4. School of Chemistry and Chemical Engineering Northwestern Polytechnical University Xi'an 710129 P. R. China
5. MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, School of Chemistry and Chemical Engineering Harbin Institute of Technology Harbin 150001 P. R. China
Abstract
AbstractFacing with serious carbon emission issues, the production of green H2 from electrocatalytic hydrogen evolution reaction (HER) has received extensive research interest. Almost all kinds of noble metal phosphides (NMPs) consisting of Pt‐group elements (i.e., Ru, Rh, Pd, Os, Ir and Pt) are all highly active and pH‐universal electrocatalysts toward HER. In this review, the recent progress of NMP‐based HER electrocatalysts is summarized. It is further take typical examples for discussing important impact factors on the HER performance of NMPs, including crystalline phase, morphology, noble metal element and doping. Moreover, the synthesis and HER application of hybrid catalysts consisting of NMPs and other materials such as transition metal phosphides, oxides, sulfides and phosphates, carbon materials and noble metals is also reviewed. Reducing the use of noble metal is the key idea for NMP‐based hybrid electrocatalysts, while the expanded functionality and structure‐performance relationship are also noticed in this part. At last, the potential opportunities and challenges for this kind of highly active catalyst is discussed.
Funder
National Natural Science Foundation of China
Cited by
14 articles.
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