Affiliation:
1. Engineering Research Center of Ministry of Education for Geological Carbon Storage and Low Carbon Utilization of Resources Beijing Key Laboratory of Materials Utilization of Nonmetallic Minerals and Solid Wastes National Laboratory of Mineral Materials School of Material Sciences and Technology China University of Geosciences (Beijing) Beijing 100083 P. R. China
2. School of Chemistry Chemical Engineering and Biotechnology Nanyang Technological University Singapore 637459 Singapore
Abstract
AbstractCO2 conversion is an anticipated route to resolve the energy crisis and environmental pollution, in which electrocatalysis is one of the technologies closest to industrialization. Alloy catalysts are promising candidates for electrocatalysis, and the high tenability in electronic structures and surface physical and chemical properties allows alloy catalysts high catalytic activity and selectivity for electrocatalytic CO2 reduction. Herein, the recent advances in alloy catalysts for electrocatalytic CO2 reduction have been systematically summarized, with insight into the structure of the active center, catalytic performance, and mechanism, to uncover the key to their high catalytic performance. The alloy catalysts are mainly classified as binary and multi‐metallic alloys (medium entropy and high entropy alloy) based on components and mixed configuration entropy, on which the relationship among the active center, catalytic performance, and mechanism has been fully discussed to inspire the rational design of alloy catalysts. Finally, the current challenges and future perspectives are presented to propose the dilemma and development direction for alloy catalysts. This review provides an overview of about the recent progress and future development of alloy catalysts to present a guideline for future research work on relevant catalysts.
Funder
National Basic Research Program of China
National Natural Science Foundation of China
Fundamental Research Funds for the Central Universities
China Scholarship Council
Subject
General Materials Science,General Chemistry
Cited by
7 articles.
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