Innovative Synthesis of Au Nanoparticle‐Trapped Flexible Macrocrystals: Achieving Stable Black Crystal Wires with Broadband Absorption

Abstract

AbstractIn optical materials, the development of absorbers for a wide spectrum is a focal point of research. A pivotal challenge lies in ensuring the stability and durability of optical absorbers, particularly at elevated temperatures. This study introduces a novel approach to creating absorbers with diverse colors, focusing on the synthesis and properties of black crystal wires. In contrast to black gold nanoparticle (Au NP) precipitates, which change color within hours under similar conditions, the method involves strategically trapping Au NPs within defects during the growth of single crystals. This results in black crystal wires that not only exhibit broadband absorption but also maintain exceptional stability even under prolonged exposure to high temperatures. The method also involves the controlled synthesis of colorless and red crystal wires. As a proof of concept, these stable black Au crystal wires demonstrate superior performance in photothermal conversion applications. The methodology, derived from the crystal growth process, presents a defect template that offers a novel approach to material design. Furthermore, these unique crystals, available in various colors, hold significant promise for a range of unexplored applications.