Affiliation:
1. Department of Construction Engineering École de technologie supérieure, Université du Québec 1100 Notre‐Dame St. W. Montreal QC H3C 1K3 Canada
2. Department of Chemistry Biology Université du Québec à Montréal 2101 Montreal QC H2X 2J6 Canada
Abstract
AbstractThe wood preservative disodium octaborate tetrahydrate (DOT) migration is studied in clay. Using boron analysis by inductively coupled plasma optical emission spectroscopy (ICP‐OES), DOT spatial and temporal dynamics are surveyed to show how DOT permeates into the wood and the clay using concentration profiles as a function of depth, initial wood moisture, and direction of filling. Atomic force microscopy and chemical imaging using photoinduced force microscopy are used to show the morphology of the wood samples and the distribution of DOT on their surface. ICP‐OES results show that the average DOT concentration in the wood samples is originally 0.8 and 1.5 wt% in the bulk and at the surface, respectively. Conditioning of the wood to a moisture content of 19% in a climatic chamber reduces DOT concentration by 8% for the fir and 17% for the spruce. After one week of contact with the clays, the results showed a rapid decrease of 25–40% in DOT concentration in wood. On longer periods (5 months), the spruce shows a tendency to reabsorb the DOT from the clay and the DOT migration stabilizes at 20%. These results contribute to defining the dosage of DOT when the wood is exposed to clay.