Affiliation:
1. School of Material Science and Engineering Henan University of Technology Lianhua Str. 100 Zhengzhou 450001 People's Republic of China
Abstract
AbstractHerein, immiscible poly(vinylidene fluoride)/poly(lactic acid) (PVDF/PLA) blends filled with multi‐walled carbon nanotubes (MWCNT) were fabricated by a facile solution flocculation method. A co‐continuous structure was formed at the blend ratio of 50v/50v. By extracting PLA, MWCNTs were found wrapped on the surface of porous PVDF. The electrical percolation threshold of porous composites is 0.25 wt.%, which is much lower than compact composites (2 wt.%). By comparing the electromagnetic interference shielding effectiveness (EMI SE) between compact and porous composites, the EMI SE of compact composites containing 15 wt.% MWCNT is ca. 30 dB, whereas 60 dB for the porous composites at the same filler loading. The enhanced shielding performance is derived from the porous structure and densely packed MWCNT on the PVDF surface that facilitates the multiple reflections of electromagnetic waves. This work provides a new thought in fabricating high performance EMI material by effectively tuning filler distribution in polymer blends.
Funder
Education Department of Henan Province
Henan University of Technology
National Natural Science Foundation of China
Subject
Materials Chemistry,Polymers and Plastics,General Chemistry,Ceramics and Composites
Cited by
3 articles.
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