Ultrafast Optical Switching by using Nanocrystals of a Halogen-Bridged Nickel-Chain Compound Dispersed in an Optical Polymer

Author:

Tao S.,Miyagoe T.,Maeda A.,Matsuzaki H.,Ohtsu H.,Hasegawa M.,Takaishi S.,Yamashita M.,Okamoto H.

Publisher

Wiley

Subject

Mechanical Engineering,Mechanics of Materials,General Materials Science

Reference17 articles.

1. χ(3) is generally defined as: P(ωσ)=ε0K(–ωσ;ω1,ω2,ω3)χ(3)(–ωσ; ω1,ω2,ω3)E(ω1)E(ω2)E(ω3). Here, P(ωσ) shows nonlinear polarization, E(ω) shows the electronic field of light, K is the numerical factor dependent on the optical configuration, and ε0 is the permittivity of a vacuum. χ(3) measured by the Z-scan method is defined as: P(ω)=0.75 ε0χ(3)(–ω;ω,–ω,ω)E(–ω)E(ω)2. χ(3) measured by the ER method is defined as: P(ω)=3 ε0χ(3)(–ω;0,0,ω)E(0)2E(ω), where E(0) is the static electric field. χ(3) measured by the THG method is defined as: P(3 ω)=0.25 ε0χ(3)(–3 ω;ω,ω,ω)E(ω)3.

2. Gigantic optical nonlinearity in one-dimensional Mott–Hubbard insulators

3. Ultrafast Optical Switching to a Metallic State by Photoinduced Mott Transition in a Halogen-Bridged Nickel-Chain Compound

4. Synthesis and crystal structure of a novel one-dimensional halogen-bridged nickel(III)-X-nickel(III) compound, {[Ni(R,R-chxn)2Br]Br2}.infin.

5. Electronic structure of the quasi-one-dimensional halogen-bridged Ni complexes [Ni(chxn)2X]X2(X=Cl, Br) and related Ni compounds

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