Regio‐ and Enantioselective Synthesis of α‐Amino‐δ‐Ketoesters Through Catalytic Umpolung Reaction of α‐Iminoesters with Enones
Author:
Affiliation:
1. Molecular Chirality Research Center, Graduate School of EngineeringChiba University, 1-33, Yayoi-cho, Inage-ku, Chiba-shi Chiba 263-8522 Japan Phone/Fax: (+81)43-290-3386
Funder
General Sekiyu R & D Encouragement Assistance Foundation and Leading Research Promotion Program ‘Soft Molecular Activation’ of Chiba University
Publisher
Wiley
Subject
General Chemistry
Link
https://onlinelibrary.wiley.com/doi/pdf/10.1002/adsc.201800791
Reference73 articles.
1. For recent reports on umpolung reactions see:
2. J. Liu C.-G. Cao H.-B. Sun X. Zhang D. Niu J. Am. Chem. Soc.2016 138 13103–13106;
3. Umpolung Addition of Aldehydes to Aryl Imines
4. Umpolung Addition of Aldehydes to Aryl Imines
5. Carbonyls as Latent Alkyl Carbanions for Conjugate Additions
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