Nucleotide‐Based Carbon Dot‐Assisted Synthesis of High Surface Area Porous α‐Ni(OH)2 as an Efficient Battery‐Type Supercapacitor Electrode

Author:

Atika 1,Dutta Raj Kumar1ORCID

Affiliation:

1. Department of Chemistry Indian Institute of Technology Roorkee Roorkee 247667 India

Abstract

Herein, a method for synthesizing highly porous single phase of α‐Ni(OH)2 via hydrothermal route is presented. Nitrogen‐ and phosphorous‐functionalized carbon dots (N,P‐CDGMP) are first synthesized by thermal refluxing of 1,5′‐guanosine monophosphate (GMP) in ethylene glycol. Then Ni(OH)2 is synthesized in the presence of N,P‐CDGMP by hydrothermal method. Microflower‐like morphology of porous nanocomposite of Ni(OH)2‐[N,P‐CDGMP] with significantly enhanced Brunauer–Emmett–Teller surface area (454 m2 g−1) is formed, which is 32 times higher than that of the pristine Ni(OH)2. The cyclic voltammetry plot suggests battery‐type supercapacitor with a specific capacity of 632 C g−1, which is 6 times higher than the pristine Ni(OH)2 (107 C g−1). The enhanced specific capacity of Ni(OH)2‐[N,P‐CDGMP] is attributable to better intercalation–deintercalation of electrolyte ions in the suitable pore volumes. Electrode kinetic studies measured at a scan rate of 0.005 V s−1 suggest that about 86% of charge is stored via diffusion‐controlled process and the charge storage by surface‐controlled capacitive process is higher at higher scan rate (e.g., at 0.1 V s−1). The application of Ni(OH)2‐[N,P‐CDGMP] is demonstrated by fabricating a hybrid supercapacitor device Ni(OH)2‐[N,P‐CDGMP]//porous activated carbon from eucalyptus wood. The retention of specific capacitance of the device is 75% after 3000 cycles with maximum energy density of 31 Wh kg−1 and power density of 0.76 kW kg−1.

Publisher

Wiley

Cited by 1 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

同舟云学术

1.学者识别学者识别

2.学术分析学术分析

3.人才评估人才评估

"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370

www.globalauthorid.com

TOP

Copyright © 2019-2024 北京同舟云网络信息技术有限公司
京公网安备11010802033243号  京ICP备18003416号-3