Graphene Quantum Dots for Photocatalytic CO2 Reduction

Author:

Sagayaraj Prince J. J.1,Augustin Ashil1,Shanmugam Mariyappan1,Honnappa Brahmari2,Natarajan Thillai Sivakumar34,Wilson Karen5,Lee Adam F.5,Sekar Karthikeyan1ORCID

Affiliation:

1. Department of Chemistry Faculty of Engineering and Technology SRM Institute of Science and Technology Kattankulathur Chennai Tamil Nadu 603203 India

2. Department of Physics and Nanotechnology SRM Institute of Science and Technology Kattankulathur Chennai Tamil Nadu 603203 India

3. Environmental Science Laboratory CSIR-Central Leather Research Institute (CSIR-CLRI) Chennai Tamil Nadu 600020 India

4. Academy of Scientific and Innovative Research (AcSIR) Ghaziabad Uttar Pradesh 600113 India

5. Centre for Catalysis and Clean Energy School of Environment and Science Griffith University 4222 Queensland Australia

Abstract

Sustainable solar fuels production through reduction of molecular CO2 using photocatalysts is an eco‐friendly and dependable source of energy for the future and for controlling the global warming. The growth of quantum dots, especially, graphene quantum dots (GQD), has emerged as a flat 0D material offering unique properties like enhanced solar light absorption, surface reactivity, charge separation, and migration efficiency, which are invariably systemizing high solar photocatalytic CO2 reduction efficiency. In this review, the insights of thermodynamics and kinetics of CO2 reduction are discussed, followed by detailed encapsulation of modification strategies of GQDs and intrinsic analysis of CO2 reduction utilizing solar light. Progressively, the challenges and futuristic outlook of GQDs‐based photocatalytic systems for solar fuels production is also presented.

Publisher

Wiley

Subject

General Energy

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