Nile Red as a Fluorescence Marker and Antioxidant for Regenerative Fuels

Author:

Lichtinger Anne1,Poller Maximilian J.1,Türck Julian23,Schröder Olaf4,Garbe Thomas5,Krahl Jürgen67,Singer Anja4,Jakob Markus4,Albert Jakob1ORCID

Affiliation:

1. Institute of Technical and Macromolecular Chemistry Hamburg University Bundesstrasse 45 20146 Hamburg Germany

2. Leuphana University Universitaetsallee 1 21335 Lueneburg Germany

3. TECOSOL GmbH Jahnstrasse 2 97199 Ochsenfurt Germany

4. Coburg University of Applied Sciences and Arts Friedrich-Streib-Strasse 2 96450 Coburg Germany

5. Volkswagen AG Berliner Ring 2 38440 Wolfsburg Germany

6. OWL University of Applied Sciences and Arts Campusallee 12 32657 Lemgo Germany

7. Fuels Joint Research Group Masch 16 38531 Rötgesbüttel

Abstract

This article contributes to the ongoing dialogue regarding the future application of renewable e‐fuels as part of a holistic solution to the energy crisis. In order to be able to continue using internal combustion engines in a sustainable manner, it must be ensured that these engines are operated exclusively with renewable, CO2‐neutral fuels. One way to achieve this is the use of a fluorescence sensor in the vehicle in combination with fuels that are labeled with a fluorescence marker. This study presents an investigation into the use of the benzophenoxazine dye Nile red as a fluorescent marker for distinguishing fossil from renewable fuels. In addition to assessing the stability of the fluorescent marker against thermo‐oxidative aging, the study probes its antioxidative impact on fuel aging, by comparing unlabeled and with Nile red labeled aged fuels. Furthermore, an examination of fuel‐specific parameters underscores the positive effect of Nile red on fuel stability. A comparison with the antioxidant butylated hydroxytoluene confirms the antioxidant effect of Nile red.

Funder

Forschungsvereinigung Verbrennungskraftmaschinen

Publisher

Wiley

Subject

General Energy

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