Coke Formation and Zeolite Catalyst Effects on Products from Co‐pyrolysis of Waste Tyre and Poplar Wood in a Semi‐Batch Reactor under N2 Atmosphere

Abstract

Herein, it is aimed to investigate the effect of zeolite catalyst on the co‐pyrolysis process of waste tyre and poplar wood. A laboratory‐sized reactor is used to pyrolyze 15 g of sample at 500 °C under atmospheric pressure. In the results, it is indicated that co‐pyrolysis affects the properties of the products. Comparing to single feedstock, the co‐pyrolysis enhances the yields of bio‐oil, while reducing the formation of char. The pyrolysis of poplar wood produces 23.3 wt% of bio‐oil, while the pyrolysis of tyre yields 25 wt% of bio‐oil. However, it is 31.29 wt% for the co‐pyrolysis process. Higher content of valuable compounds are formed in the bio‐oil, which improve the fuel properties of the bio‐oil. The zeolite catalyst alters the characteristics of the products obtained from the co‐pyrolysis process. The gaseous products show a decrease in the concentrations of carbon monoxide and carbon dioxide when the catalyst is present. The liquid product analysis reveals the presence of light aromatics such as ethyl benzene and light linear compounds such as alkanes including octane, hexane, etc. The analysis of the catalysts suggests that a very small amount of coke deposits on the catalyst due to the slight increase in carbon content.