Affiliation:
1. School of Materials Science and Engineering China University of Petroleum (East China) Qingdao 266580 P. R. China
Abstract
A facile approach is developed for the preparation of an oxygen reduction reaction (ORR) catalyst Co–N–GA‐1 by pyrolyzing a well‐designed precursor CoTPP/H2TPP@OGA. In the precursor, Co is preanchored into the porphyrinato cobalt CoTPP molecule by Co‐N4 core that is further protected by the metal‐free porphyrin H2TPP depending on the intermolecular π–π interaction during the self‐assembled process on the surface of lipophilic porous original graphene aerogel. The resulted Co–N–GA‐1 owns a Co elemental content up to 1.67%, which is ≈13 times than that of Co‐N‐CB‐1 originated from a CoTPP/H2TPP precursor absorbed on commercial carbon black. Meanwhile, CoN content accounts for 71.7% of the total Co‐based species in the Co–N–GA‐1, more than that of CoN‐GA‐2 (58.9%) originated from the CoTPP@OGA precursor. Consequently, Co–N–GA‐1 exhibits the most ORR performance among the present three catalysts with the more positive onset and half‐wave potentials of 0.96 and 0.88 V vs reversible hydrogen electrode, respectively, also superior to those of the commercial 20 wt% Pt/C and most of the Co‐based catalysts reported so far. Furthermore, Zn‐air battery assembled with Co–N–GA‐1 exhibits a higher peak power density of 110 mW cm−2 and excellent durability than that with Pt/C.
Funder
National Natural Science Foundation of China
Cited by
2 articles.
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