Iron‐Based Sulfate for Sodium‐Ion Batteries: Past, Present, and Future

Author:

Liu Zhaolu1,Wang Ning2,Wang Ruiqi3,Xu Jie4,Zhang Hao1,Wang Nan5,Cao Yongjie5ORCID,Liu Yao6ORCID,Zhang Junxi1ORCID

Affiliation:

1. Shanghai Key Laboratory of Materials Protection and Advanced Materials in Electric Power Shanghai University of Electric Power Shanghai 200090 P. R. China

2. Department of Chemistry College of Sciences Shanghai University Shanghai 200444 P. R. China

3. National & Local Joint Engineering Laboratory for Optical Conversion Materials and Technology, School of Materials and Energy Lanzhou University Lanzhou Gansu 730000 P. R. China

4. School of Materials Science and Engineering Anhui University of Technology Ma'anshan 243002 P. R. China

5. Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials Fudan University Shanghai 200433 P. R. China

6. Key Laboratory of Interfacial Physics and Technology Shanghai Institute of Applied Physics, Chinese Academy of Sciences Shanghai 201800 P. R. China

Abstract

Sodium‐ion batteries (SIBs) are crucial energy equipment that sustain low cost and better environmental benefit. Nevertheless, the practical energy density of SIBs is limited by cathode material. Over last decades, the iron‐based sulfate (IBS) has been extensively studied owing to its numerous advantages, including a large theoretical specific energy (over 100 Wh kg−1), high working potential (above 3.4 V), low cost, good structural stability, and environmental friendliness. Nevertheless, the application of IBS in SIBs is limited by its unsuitable electrolyte and low electronic/ionic conductivity. This review summarizes recently developed results on IBS materials for SIBs, ranging from the phase diagram–composition structure–electrochemical performance to modification research. A generalized summary of the future prospects of IBS‐based materials is also provided, with the hope of inspiring further advances in their application in SIBs.

Funder

Shanghai Municipal Key Laboratory of Intelligent Information Processing, Science and Technology Commission of Shanghai Municipality

Publisher

Wiley

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