Parasitic Effects in Impedance Spectrum of PEM Water Electrolysis Cells: Case Study of High‐Frequency Inductive Effects

Author:

Franzetti Irene1ORCID,Pushkarev Artem12,Chan Ai-Lin3,Smolinka Tom1

Affiliation:

1. Chemical Energy Storage Fraunhofer Institute for Solar Energy System ISE Heidenhofstrasse 2 D-79110 Freiburg Germany

2. HySA Infrastructure Center of Competence Faculty of Engineering North-West University Private Bag X6001, Potchefstroom Campus 2531 South Africa

3. Chemical and Material Sciences Center National Renewable Energy Laboratory 15013 Denver West Parkway Golden CO 80401 USA

Abstract

Electrochemical impedance spectroscopy (EIS) is a powerful tool to characterize and distinguish electrochemical, electrical, and diffusive processes in an electrolysis cell. The EIS response with small impedance (mΩ) depends on components and materials of the cell, but often also on the electrical setup, cables, and connectors, leading to incorrect conclusions about the performance of the electrolysis cells. These parasitic effects are assessed via a short‐circuit measurement and confirmed to be external from the membrane electrode assembly (MEA). In the setup, the inductive characteristic is described by a modified inductive reactance and must be included in the equivalent circuit model (ECM) which is fitting the cell EIS spectra in operation (in situ). If points of the spectra showing inductive characteristic (below x‐axis in Nyquist plot) are excluded from the ECM evaluation, an artificially increased ohmic resistance at high frequencies is obtained. In addition, considerations on other components of the ECM can be misleading and significantly incorrect. The only way to avoid that inductive behavior caused by the external setup is incorrectly assigned to the ECM describing properties of the MEA is to include the inductive effects in the ECM analysis of in situ EIS measurements.

Funder

Fraunhofer-Gesellschaft

Publisher

Wiley

Subject

General Energy

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