Kinetics and Mechanism of Hydrogen‐Atom Abstraction from Rhodium Hydrides by Alkyl Radicals in Aqueous Solutions
Author:
Affiliation:
1. Ames Laboratory, Iowa State University, Ames, IA 50011 (USA), Fax: (+1) 515‐294‐4709
2. Chemistry Department, Iowa State University, Ames, IA 50011 (USA)
Publisher
Wiley
Subject
General Chemistry,Catalysis,Organic Chemistry
Link
https://onlinelibrary.wiley.com/doi/pdf/10.1002/chem.201100094
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2. Hydricities of d6 Metal Hydride Complexes in Water
3. Reversible Formation of Bis(2,2‘-bipyridine)rhodium(III) Dihydride from Bis(2,2‘-bipyridine)rhodium(I) and Dihydrogen. Direct Transfer of Dihydrogen from Rhodium(III) Dihydride to Rhodium(I)
4. Aqueous rhodium(iii) hydrides and mononuclear rhodium(ii) complexes
5. Aqueous Biphasic Hydrogenations
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1. O2 Insertion into Group 9 Metal–Hydride Bonds: Evidence for Oxygen Activation through the Hydrogen-Atom-Abstraction Mechanism;Inorganic Chemistry;2012-08-10
2. Computational Investigations into Hydrogen‐Atom Abstraction from Rhodium Hydride Complexes by Methyl Radicals in Aqueous Solution;European Journal of Inorganic Chemistry;2011-09-23
3. Kinetics and mechanism of the reduction of a macrocyclic Rh(iii) complex by chromium(ii) ions: pH-controlled selectivity to rhodium(ii) vs. rhodium(iii) hydride;Dalton Transactions;2011
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