Aminomethyl Transfer (Mannich) Reactions Between an O‐Triethylsilylated Hemiaminal and Anilines, R n C 6 H 5− n NH 2 Leading to New Diamines, Triamines, Imines, or 1,3,5‐Triazines Dependent upon Substituent R
Author:
Affiliation:
1. Department of ChemistryUniversity of Texas at El Paso El Paso TX. 79968-0513 USA
Funder
Welch Foundation
Publisher
Wiley
Subject
General Chemistry,Catalysis,Organic Chemistry
Link
https://onlinelibrary.wiley.com/doi/pdf/10.1002/chem.201901877
Reference38 articles.
1. Siloxymethylamines as Aminomethylation Reagents for Amines Leading to Labile Diaminomethanes That can be Trapped as Their [Mo(CO) 4 ] Complexes
2. Triethylsiloxymethyl-N,N-dimethylamine, Et3SiOCH2NMe2: A Dimethylaminomethylation (Mannich) Reagent for O-H, S-H, P-H and Aromatic C-H Systems
3. Synthesis of a “Super Bulky” Guanidinate Possessing an Expandable Coordination Pocket
4.
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1. Reactions of Aldehydes and Ketones and Their Derivatives;Organic Reaction Mechanisms Series;2023-01-20
2. Aminomethylation of Aminoferrocene, [(η5-C5H5)Fe(η5-C5H4NH2)], and (Anilino)chromiumtricarbonyl, [(η6-C6H5NH2)Cr(CO)3], by O-Triethylsilyl-hemiaminal, (Et3SiOCH2NMe2): The Role of Disparate Organometallic Electronic Effects in Modifying Product Outcomes;Organometallics;2022-04-08
3. Aminomethylation of Thioureas with N,N-Dimethyl-1-(triethylsiloxy)methanamine, Involving Amino Group Exchange;Russian Journal of Organic Chemistry;2019-11
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