Nickel/α‐diimine catalysts in C (sp2)–C (sp2) homocoupling: An underestimated and versatile ligand family

Author:

Kudakina Vera A.1ORCID,Asachenko Andrey F.1,Valaeva Valentina N.1,Lebedev Artyom Y.1ORCID,Razavi Abbaz2,Mladentsev Dmitry Y.1,Uborsky Dmitry V.1ORCID,Voskoboynikov Alexander Z.1

Affiliation:

1. Department of Chemistry Lomonosov Moscow State University 1/3 Leninskie Gory Moscow 119991 Russian Federation

2. Total Petrochemicals Research Zone Industrielle C Feluy B‐7181 Belgium

Abstract

Application of α‐diimine ligands in Ni‐catalyzed reductive homocoupling of haloarenes is reported. The Ni/α‐diimine catalysts are shown to be highly active and allow for preparation of a broad scope of biaryls, including practically important cyclization and polycondensation products. The synthetic availability and versatility of α‐diimines allows for easy tuning of their structure aimed at achieving higher yields of each specific homocoupling product.

Publisher

Wiley

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