Affiliation:
1. State Key Laboratory of Fine Chemicals Frontier Science Center for Smart Materials Liaoning Key Laboratory for Catalytic Conversion of Carbon Resources and School of Chemical Engineering Dalian University of Technology Dalian 116024 P. R. China
2. School of Chemistry and Chemical Engineering in‐situ Center for Physical Sciences Frontiers Science Center for Transformative Molecules, and Energy Device Research Center (SEED) Shanghai Jiao Tong University Shanghai 200240 P. R. China
Abstract
AbstractP2‐type layered oxide material Na2/3Ni1/3Mn2/3O2 is a competitive candidate for sodium‐ion batteries (SIBs). Nevertheless, it suffers from the strong P2–O2 phase transition during charging to the high voltage regime, rendering drastic volume variations and poor cycling performance. Here, a Quasi‐zero strain P2‐Na0.75Li0.15Mg0.05Ni0.1Mn0.7O2 cathode is synthesized, which reflects the vanishing P2–O2 transition with a volume change as low as 0.49%, thus resulting in the material an excellent cycling performance (83.9% capacity retention after 500 cycles at 5 C). The low‐volume strain can be attributed to two aspects: (1) the Mg2+ riveted in the Na layer can act as a “pillar” to stabilize the crystal structure under the condition of sodium removal, thus restricting the structural changes under high voltage. (2) The entry of Li+ into the transition metal (TM) layer can mitigate the electron localization in the highly desodiation state and can effectively immobilize the coordination oxygen atoms, thus suppressing the slip of P2–O2 transition. This study not only provides a new insight of Li and Mg synergetic substitution effect on the structural stability of P2‐type cathode, but also an efficient avenue for developing cathode materials of SIBs with ultralow bulk strain.
Funder
National Natural Science Foundation of China
Fundamental Research Funds for the Central Universities
Subject
Electrochemistry,Condensed Matter Physics,Biomaterials,Electronic, Optical and Magnetic Materials
Cited by
8 articles.
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