Visible‐Light Responsive Ionic Columnar Self‐Assemblies Exhibiting Fast Photothermal Energy Conversion at Room‐Temperature

Abstract

AbstractA visible‐light responsive ionic liquid crystalline (LC) system based on gallic ester and tetra‐ortho‐substituted azobenzene is designed and synthesized. All the prepared derivatives exhibit columnar hexagonal mesophases at room temperature either in their pristine form or on cooling from isotropic states. The strategic design of these molecules allows for rapid photoisomerization, which is further aided by the dynamic LC phase. These systems attains photostationary states (PSSs) within 5 min of charging and discharging. The maximum Z conversion on charging in the solid‐state at room‐temperature is ≈80% with a highest temperature rise of 9.1 °C on discharging. This new molecular design enables the efficient working of solar thermal fuels (STFs) even in low sunlight intensity conditions, potentially promoting widespread adoption for mitigating global energy demands.