Revealing the Structure/Property Relationships of Semiconductor Nanomaterials via Transmission Electron Microscopy

Author:

Zhao Peili1,Cheng Yongfa2,Li Lei3,Jia Shuangfeng1,Guan Xiaoxi1,Huang Tianlong1,Li Luying2,Zheng He1,Wang Jianbo13ORCID

Affiliation:

1. School of Physics and Technology Center for Electron Microscopy MOE Key Laboratory of Artificial Micro‐ and Nano‐structures and Institute for Advanced Studies Wuhan University Wuhan 430072 China

2. Wuhan National Laboratory for Optoelectronics (WNLO) and School of Optical and Electronic Information Huazhong University of Science and Technology (HUST) Wuhan Hubei 430074 China

3. Core Facility of Wuhan University Wuhan 430072 China

Abstract

AbstractTransmission electron microscopy (TEM) offers unprecedent atomic resolution imaging and diverse characterizations capabilities, which has been proved to be effective in correlating the atomic structures and compositions with the physical/chemical properties of semiconductor nanomaterials. This review aims to provide an overview of the latest advancements regarding the atomic structure/property relationship in semiconductor nanomaterials. First, by employing off‐axis electron holography, a comprehensive overview of the quantitative investigations into the atomic‐electronic structure relationship of semiconductors is presented. Second, by integrating in situ TEM technique with micro/nanoelectromechanical systems (M/NEMS), this review summarizes the recent advancements achieved in elucidating the intricate relationship between structure and properties of nanomaterials subjected to diverse stimuli such as stress, thermal, and electric fields. Moreover, the impact of electron beam irradiation on the microstructure of semiconductor nanomaterials is discussed. Lastly, current challenges and future research opportunities are proposed along with their potential applications.

Funder

National Natural Science Foundation of China

National Key Research and Development Program of China

Science Fund for Distinguished Young Scholars of Hubei Province

Fundamental Research Funds for the Central Universities

Publisher

Wiley

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