Affiliation:
1. Hefei National Research Center for Physical Sciences at the Microscale and Department of Materials Science & Engineering University of Science and Technology of China Hefei 230026 China
2. The High Magnetic Field Laboratory Hefei Institutes of Physical Science Chinese Academy of Sciences Hefei 230031 China
Abstract
AbstractInspired by the d‐band center theory, previous studies mainly focus on transition metals as electrocatalytic active sites. The s‐block metals in the periodic table, especially group ΙA metals with fewer valence electrons, are rarely reported as high‐activity electrocatalysts for reduction reactions due to the difficulties associated with their electronic structure regulation. Herein, theoretical calculations demonstrate that group ΙA element lithium (Li) embedded in N, O‐doped graphene is an effective electrocatalytic active center for carbon dioxide reduction reaction (CO2RR) and oxygen reduction reaction (ORR). This catalytic feasibility results from the s–p orbital hybridization between originally empty 2p orbital of Li and the orbitals of coordinated atoms. This vacant 2p orbital can serve as a site for additional p–π conjugation between Li and N, O‐doped graphene. Theoretically, the zigzag‐type Li–O2 model shows remarkable CO2RR activity, while Li–pyridinic–N1‐C1 exhibits high ORR activity. Furthermore, a carbon‐based catalyst with well‐anchored Li atoms coordinated to N, O substituents is experimentally demonstrated to exhibit exceptional CO2RR activity (FECO = 98.8% at −0.55 V) and ORR performance in acidic media (E1/2 = 0.77 V). This is the first report on bifunctional high‐performance electrocatalyst utilizing a group ΙA element with performance comparable to that of most previously reported transition‐metal‐based catalysts.
Funder
National Natural Science Foundation of China
National Key Research and Development Program of China
Subject
Electrochemistry,Condensed Matter Physics,Biomaterials,Electronic, Optical and Magnetic Materials
Cited by
3 articles.
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