Affiliation:
1. Department of Chemistry Hong Kong University of Science and Technology (HKUST) Clear Water Bay Rd Kowloon Hong Kong SAR 999077 China
2. Department of Physics Hong Kong University of Science and Technology (HKUST) Clear Water Bay Rd Kowloon Hong Kong SAR 999077 China
Abstract
AbstractProducing efficient blue and deep blue perovskite LEDs (PeLEDs) still represents a significant challenge in optoelectronics. Blue PeLEDs still have problems relating to color, luminance, and structural and electrical stability so new materials are needed to achieve better performance. Recent reports suggest using low n states (n = 1, 2, 3) to achieve blue electroluminescence in Ruddlesden–Popper (RP) perovskite films. However, there are fewer reports on the other quasi‐2D structure, Dion–Jacobson (DJ) perovksites, despite their highly desirable optical properties, due to the difficulty in achieving charge injection. To resolve this issue, herein, w e have mixed DJ phase precursors, propane‐1,3‐diammonium (PDA) bromide into RP phase perovskites and fabricated low‐dimensional PeLEDs. It is found that these specific precursors aid in suppressing both the low n (n = 1) and high n (n ≥ 4) quasi‐2D RP phases and is an effective strategy in blue‐shifting sky‐blue RP perovskites into the sub‐470 nm region. With optimization of the PDA concentration and device layers, it is achieved an external quantum efficiency of 1.5% at 469 nm and stable electroluminescence for the first deep blue PeLED to be reported using DJ perovskites.
Subject
Electrochemistry,Condensed Matter Physics,Biomaterials,Electronic, Optical and Magnetic Materials
Cited by
7 articles.
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