Real Competitors to Ruby: The Triel Oxonitridoborates AlB4O6N, Al0.97Cr0.03B4O6N, and Al0.83Cr0.17B4O6N-Reference-Cited by-同舟云学术

Real Competitors to Ruby: The Triel Oxonitridoborates AlB₄O₆N, Al_0.97Cr_0.03B₄O₆N, and Al_0.83Cr_0.17B₄O₆N

Published:2024-03-07 Issue:28 Volume:34 Page:
ISSN:1616-301X
Container-title:Advanced Functional Materials
language:en
Short-container-title:Adv Funct Materials

Author:

Widmann Ingo¹^ORCID,Kinik Gülsüm²^ORCID,Jähnig Maximilian³,Glaum Robert³^ORCID,Schwarz Marcus⁴,Wüstefeld Christina⁵^ORCID,Johrendt Dirk⁶^ORCID,Tribus Martina⁷,Hejny Clivia⁷^ORCID,Bayarjargal Lkhamsuren⁸^ORCID,Dubrovinsky Leonid⁹^ORCID,Heymann Gunter¹^ORCID,Suta Markus²^ORCID,Huppertz Hubert¹^ORCID

Affiliation:

1. Department of General Inorganic and Theoretical Chemistry University of Innsbruck Innrain 80–82 Innsbruck 6020 Austria

2. Inorganic Photoactive Materials Institute of Inorganic & Structural Chemistry Heinrich Heine University Düsseldorf Universitätsstraße 1 40225 Düsseldorf Germany

3. Department of Inorganic Chemistry Rheinische Friedrich‐Wilhelms‐Universität Bonn Gerhard‐Domagk‐Straße 1 53121 Bonn Germany

4. Institute of Inorganic Chemistry TU Bergakademie Freiberg Leipziger Straße 29 09596 Freiberg Germany

5. Institute of Materials Science TU Bergakademie Freiberg Gustav‐Zeuner‐Straße 5 09599 Freiberg Germany

6. Department of Chemistry Ludwig‐Maximilians‐Universität München Butenandtstraße 5–13 (Haus D) 81377 München Germany

7. Department of Mineralogy and Petrography University of Innsbruck Innrain 52f Innsbruck 6020 Austria

8. Institute of Geosciences Goethe‐Universität Frankfurt am Main Altenhöferallee 1 60438 Frankfurt am Main Germany

9. Universität Bayreuth Bayerisches Geoinstitut 95440 Bayreuth Germany

Abstract

AbstractAlB4O6N, Al0.97Cr0.03B4O6N, and Al0.83Cr0.17B4O6N are the first representatives of the recently established structure‐family of oxonitridoborates containing Al3+. These compounds are isotypic to CrB4O6N and are synthesized in a multi‐anvil press under high‐pressure/high‐temperature conditions of 7.0 GPa/1350 °C. Structural refinement by single‐crystal X‐ray diffraction shows that they crystallize in the space group P63mc (no. 186) with two formula units per cell. Detailed characterization including high‐temperature X‐ray powder diffraction (HT‐XRD), electron probe microanalysis (EPMA), measurements of second harmonic generation (SHG), hardness, photoluminescence properties, vibrational spectroscopy, and band structure calculations reveal intriguing physicochemical properties that strongly resemble the famous material ruby.

Publisher

Wiley

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/adfm.202400054

Reference73 articles.

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