Affiliation:
1. Department of Chemistry Indian Institute of Technology Guwahati Guwahati Assam 781039 India
2. Department of Mechanical Engineering Ben‐Gurion University of the Negev Be'er Sheva 8410501 Israel
Abstract
AbstractIn recent years, the application of ionic thermoelectric (TE) materials to convert low‐grade waste heat into electricity has become a subject of intense scientific research. However, most of the efforts are focused on organic polyelectrolytes or ionic‐liquids embedded in polymeric gels. Here, for the first time, it is demonstrated that nanofluidic membranes of reconstructed layered materials like vanadium pentoxide (V2O5) exhibit excellent ionic‐TE characteristics. The high Seebeck coefficient (S = 14.5 ± 0.5 mV K‐1) of the V2O5 membrane (VO‐M) is attributed to temperature gradient‐induced unidirectional transport of protons through the percolated network of 2D nanofluidic channels. The TE characteristics of VO‐M show nearly 80% improvement (S = 26.3 ± 0.7 mV K‐1) upon functionalizing its percolated network with ionic polymers like poly(4‐styrenesulfonic acid) (PSS). Further, unlike organic polymer‐based TE systems, VO‐M not only sustains exposure to high temperatures (≈200 °C, 5 min) but also protects the PSS molecules intercalated into its interlayer space. Moreover, V2O5‐based TE materials can self‐repair any damage to their physical structure with the help of a tiny water droplet. Thus, nanofluidic membranes of reconstructed layered materials like VO‐Ms demonstrate vast robustness and great ionic‐TE performance, which can provide a novel platform for scientific studies and futuristic applications.
Funder
Israel Science Foundation
Subject
Electrochemistry,Condensed Matter Physics,Biomaterials,Electronic, Optical and Magnetic Materials
Cited by
4 articles.
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