Affiliation:
1. Hubei Key Laboratory of Electrochemical Power Sources College of Chemistry & Molecular Science Wuhan University Wuhan 430072 China
2. State Key Laboratory of New Textile Materials & Advanced Processing Technologies Wuhan Textile University Wuhan 430072 China
Abstract
AbstractMany organic solvents have excellent solution properties, but fail to serve as lithium‐ion batteries (LIBs) electrolyte solvents, due to their electrochemical incompatibility with graphite anodes. Herein, a new strategy is proposed to address this issue by introducing a surface‐adsorbed molecular layer to regulate the interfacial solvation structure without the alteration of electrolyte composition and properties. As a proof‐of‐concept study, it is demonstrated for the first time that the intrinsically incompatible propylene carbonate (PC)‐based electrolyte becomes completely compatible with graphite anodes by introducing a layer of adsorbed hexafluorobenzene (HFB) molecules to weaken the Li+‐PC coordination strength and facilitate the interfacial desolvation process. As a consequence, the graphite/ NCM811 pouch cells using the PC‐based electrolyte containing only 1 vol.% HFB demonstrate excellent long‐term cycling stabilities over 1150 cycles. This strategy is also proved to be applicable to other ethylene carbonate (EC)–free electrolytes, thus providing a new avenue for developing advanced LIB electrolytes.
Funder
National Natural Science Foundation of China
Fundamental Research Funds for the Central Universities
Subject
Electrochemistry,Condensed Matter Physics,Biomaterials,Electronic, Optical and Magnetic Materials
Cited by
2 articles.
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