Affiliation:
1. Key Laboratory of Flexible Electronics (KLOFE) & Institute of Advanced Materials (IAM) & School of Flexible Electronics (Future Technologies) Nanjing Tech University (Nanjing Tech) Nanjing 211816 China
2. School of Physical Science and Information Technology Liaocheng University Liaocheng 252059 China
3. Yunlong Lake Laboratory of Deep Earth Science and Engineering Xuzhou 221116 China
4. School of Chemistry & Materials Science Jiangsu Normal University Xuzhou 221116 China
Abstract
AbstractEpidermal patches utilized for the transduction of biopotentials and biomechanical signals are pivotal in wearable health monitoring. However, the shortcomings, such as inferior conformal ability, deficient adhesion, and motion artifacts, severely impede the bioelectrodes from perceiving stable and superior‐quality physiological signals. Herein, a polymer epidermal patch possessing a spontaneous Janus structure is facilely prepared through itaconic acylhydrazine (IAH) induced gradient polymerization. The solubility discrepancy of the monomers in IAH authorized the Janus structure with distinct adhesion properties on each side. Moreover, the hydrogen bond network constructed by IAH confers the polymer with a high degree of skin compliance, enabling dynamic and stable mechanical properties to withstand complex monitoring environments. By integrating skin‐like softness (Young's modulus ≈0.16 MPa), robust adhesion (35 kPa), and high signal‐to‐noise ratio (32 dB), this epidermal patch displays exceptional elasticity within the physiological activity spectrum, provides swift electrical and mechanical self‐recovery capabilities, and resists interference in dynamic signal monitoring (deformation, compression, humidity, etc.). By demonstrating multifaceted applications for Electrocardiogram recording under diverse disturbances, the epidermal patch profiles a promising noninvasive, enduring wearable bioelectronic interface with immunity to interference.
Funder
National Natural Science Foundation of China