Synthesis of Highly Stable LTO/rGO/SnO2 Nanocomposite via In Situ Electrostatic Self‐Assembly for High‐performance Lithium‐Ion Batteries

Author:

Wang Ming12,Fang Peng Fei1,Chen Ying1,Leng Xin Yang1,Yan Yong3,Yang Shao Bin12,Xu Ping4,Yan Cheng5

Affiliation:

1. School of Materials Science and Engineering Liaoning Technical University 47 Zhonghua Road Fuxin Liaoning 123000 P. R. China

2. Key Laboratory of Mineral High Value Conversion and Energy Storage Materials of Liaoning Province Fuxin Liaoning 123000 P. R. China

3. School of Beijing University of Technology Beijing Beijing 100124 P. R. China

4. School of Mechanical Engineering Liaoning Technical University 47 Zhonghua Road Fuxin Liaoning 123000 P. R. China

5. School of Mechanical Medical and Process Engineering Faculty of Engineering Queensland University of Technology 2 George St Brisbane Queensland 4000 Australia

Abstract

AbstractThe practical application of spinel‐type lithium titanate Li4Ti5O12 (LTO) lithium‐ion batteries is hindered by its poor conductivity and relatively low capacity. To address these issues, an LTO/reduced graphene oxide (rGO)/SnO2 is synthesized via an in situ electrostatic self‐assembly and hydrothermal reduction process. Density function theory (DFT) simulations are conducted to understand the geometrical structures of these composites and the energy storage mechanisms. The DFT results confirm that the introduction of rGO and SnO2 to LTO increases the overall conductivity, improves the structure stability, and increases Li‐ion diffusion speed.

Publisher

Wiley

Subject

Electrochemistry,Condensed Matter Physics,Biomaterials,Electronic, Optical and Magnetic Materials

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