Eliminating the Reverse ISC Bottleneck of TADF Through Excited State Engineering and Environment‐Tuning Toward State Resonance Leading to Mono‐Exponential Sub‐µs Decay. High OLED External Quantum Efficiency Confirms Efficient Exciton Harvesting

Author:

Yersin Hartmut1ORCID,Czerwieniec Rafał1ORCID,Mataranga‐Popa Larisa1,Mewes Jan‐Michael2ORCID,Cheng Gang345ORCID,Che Chi‐Ming34ORCID,Saigo Masaki6,Kimura Shuji6,Miyata Kiyoshi6ORCID,Onda Ken6ORCID

Affiliation:

1. Institute for Physical Chemistry University of Regensburg 93040 Regensburg Germany

2. Mulliken Center for Theoretical Chemistry University of Bonn 53115 Bonn Germany

3. State Key Laboratory of Synthetic Chemistry HKU‐CAS Joint Laboratory on New Materials Department of Chemistry The University of Hong Kong Pokfulam Road Hong Kong SAR China

4. HKU Shenzhen Institute of Research and Innovation Shenzhen 518053 China

5. Hong Kong Quantum AI Lab Limited 17 Science Park West Avenue Pak Shek Kok Hong Kong SAR China

6. Department of Chemistry Faculty of Science Kyushu University Fukuoka 819‐0395 Japan

Funder

North Carolina State University

Development and Reform Commission of Shenzhen Municipality

Applied Basic Research Key Project of Yunnan

Publisher

Wiley

Subject

Electrochemistry,Condensed Matter Physics,Biomaterials,Electronic, Optical and Magnetic Materials

Reference77 articles.

1. Triplet-singlet emission in fluid solutions. Phosphorescence of eosin

2. H.Yersin U.Monkowius Komplexe mit kleinen Singulett‐Triplett Energie‐Abständen zur Verwendung in opto‐elektronischen Bauteilen (Singulett Harvesting Effekt). Internal patent filing University of Regensburg2006 Patent DE 10 2008 033563 2008.

3. Highly Phosphorescent Bis-Cyclometalated Iridium Complexes:  Synthesis, Photophysical Characterization, and Use in Organic Light Emitting Diodes

4. Nearly 100% internal phosphorescence efficiency in an organic light-emitting device

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