Interlayer Injection of Low‐Valence Zn Atoms to Activate MXene‐Based Micro‐Redox Capacitors With Battery‐Type Voltage Plateaus

Author:

Cao Zhiqian1,Liang Guojin2,Ho Derek23,Zhi Chunyi2,Hu Haibo1ORCID

Affiliation:

1. School of Materials Science and Engineering Key Laboratory of Structure and Functional Regulation of Hybrid Materials Ministry of Education Anhui University Hefei 230601 China

2. Department of Materials Science and Engineering City University of Hong Kong Kowloon 999077 China

3. Hong Kong Center for Cerebro-Cardiovascular Health Engineering Innovation and Technoloyy commision Hong Kong 999077 China

Abstract

AbstractInsufficient and unstable energy output is the bottleneck issue radically restricting the application of micro‐supercapacitors (MSCs). Herein, an interlayer atom injection strategy that can anchor low‐valence Zn atoms (Znδ+, 0 < δ <2) on O‐terminals of Ti3C2Tx (MXene) flakes within the MXene/silver‐nanowires hybrid cathode of symmetric MSCs is first presented. Combining the polyacrylamide/ZnCl2 hydrogel electrolyte rich in Cl and Zn2+ ions, the matched Znδ+/Zn2+ (−0.76 V vs SHE) and Ag/AgCl (0.23 V vs SHE), redox couples between the symmetrical electrodes are activated to offer faradaic charge storage beside ions‐intercalation involved pseudocapacitance. Thus, a battery‐type voltage plateau (≈0.9 V) appears in the discharge curve of a fabricated pseudo‐symmetric micro‐redox capacitor, simultaneously achieving energy density enhancement (117 µWh cm−2 at 0.5 mA cm−2) and substantially improved power output stability (46% of the energy from the plateau region) relative to that before activation (98 µWh cm−2 without voltage platform). The work provides a fire‐new strategy to overcome the performance bottlenecks confronting conventional MSCs.

Funder

National Natural Science Foundation of China

Publisher

Wiley

Subject

Electrochemistry,Condensed Matter Physics,Biomaterials,Electronic, Optical and Magnetic Materials

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