Affiliation:
1. State Key Laboratory of Catalysis Dalian Institute of Chemical Physics Chinese Academy of Sciences 457 Zhongshan Road Dalian 116023 China
2. University of Chinese Academy of Sciences 19A Yuquan Road Beijing 100049 China
Abstract
AbstractRobust high‐valence metal–organic framework (MOF) membranes for CO2 separations show great promise for achieving carbon neutrality. Herein, the elegant fabrication of tetravalent zirconium Materials of Institute Lavoisier‐140A (MIL‐140A) membranes are pioneered and validated the intriguing dual role for both CO2‐selective and CO2‐rejective separations by combining structural regulation with the exploitation of the appropriate anisotropic ultramicropores. This inimitable separation ability of “hitting two targets with one arrow” with distinctive molecular size cut‐offs, which originated from the significant orientation transformation, enables the membranes to satisfy multiscenario CO2 capture requirements. The preferred (h0h)‐oriented MIL‐140A membranes exhibit superior mixed CO2/CH4 separation capacities (a separation factor of ≈30), while the highly (200)‐oriented MIL‐140A membranes exhibit remarkable mixed H2/CO2 separation capacities (a separation factor of ≈540), and they both ranked at the top among the present MOF membranes. This work highlights the promising prospects of the fresh MIL‐140 series for a given membrane‐based multiscenario CO2 separation application through microstructure customization and manipulation.
Funder
National Natural Science Foundation of China
National Key Research and Development Program of China